An optical waveguide capable of having various characteristics and a
method of manufacture thereof as well as a method of manufacturing a
crystal film are provided. An optical functional material
KTa.sub.xNb.sub.1-xO.sub.3 is used as an optical waveguide. The input
optical signal is transmitted to the KTa.sub.xNb.sub.1-xO.sub.3 film. The
KTa.sub.xNb.sub.1-xO.sub.3 film undergoes changes in optical property
when an external voltage signal is applied to the electrode. Therefore,
as it passes through the KTa.sub.xNb.sub.1-xO.sub.3 film, the input
optical signal is modulated by the characteristic change. The modulated
optical signal is taken out as an output optical signal.