Forming a hollow structure having an internal coating includes the steps of placing a core shaped to form the internal surface of the structure in a mould, filling the mould with a material powder, hot isostatically pressing the powder about the mould to consolidate the powder, and removing the core from the hollow structure formed, wherein a coating is applied to the core prior to placement in the mould, which coating bonds to the hollow structure formed, during the hot isostatic pressing, to form the internal coating.