The use of conductive polyaniline fibers for resistive heating
applications is described. Unlike metal wires and conductive-polymer
coated fibers, under certain conditions, electric voltages or currents
used to generate heat in the fibers were found to produce irreversible
changes to the polymer backbone that destroy its electrical conductivity
but not its structural integrity. The temperature that these changes
occur varies with dopant and fiber diameter, and can be tailored to
specific applications. Since these changes occur at lower temperatures
than the temperature at which dopant molecules within the conductive
polymer are lost or decomposed, both of which lower the conductivity of
the material, polyaniline fibers can be used for resistive heating
applications where the heating element is in the vicinity of the skin of
the wearer thereof.