Process for the production of olefins such as ethylene from a hydrocarbon
such as ethane. The process involves passing a mixture of the hydrocarbon
and an oxagen-containing gas through a catalyst zone which is capable of
supporting combustion beyond the fuel rich limit of flammability to
produce the olefin. The catalyst zone comprises at least a first catalyst
bed and a second catalyst bed. The second catalyst bed is located
downstream of the first catalyst bed, is of a different composition to
the first catalyst bed and comprises at least one metal selected from the
group consisting of Mo, W, and groups IB, IIB, IIIB, IVB, VB, VIIB and
VIII of the Periodic Table. Suitably, the first catalyst bed comprises
platinum and the second catalyst bed comprises tin- or copper-promoted
nickel, cobalt or iridium catalyst or a copper-only catalyst.