This invention relates to a novel fluidized bed membrane reactor for
autothermal operations. More particularly, this invention pertains to a
unique fluidized bed membrane reactor which includes internal catalyst
solids circulation for conveying heat between a reforming zone and an
oxidation zone. A method of producing hydrogen gas from a hydrocarbon gas
and steam comprising forming a fluidized bed of a suitable particulate
catalyst in a reactor, wherein the catalyst is disposed in the reactor in
two reaction modes, the first being an endothermic dehydrogenation
reaction mode and the second being an exothermic oxidation or partial
oxidation reaction mode, introducing a mixture of steam and hydrocarbon
gas into the bottom of the fluidized bed to fluidize the particulate
catalyst and form the fluidized bed, reacting the steam and hydrocarbon
gas within the first endothermic dehydrogenation reaction mode to produce
hydrogen gas, separating said hydrogen gas from other gases in the first
endothermic dehydrogenation reaction mode as molecular or atomic hydrogen
through a perm-selective membrane that permits the transfer of hydrogen
therethrough while preventing or minimizing the transmission therethrough
of the other gases in the endothermic dehydrogenation reaction mode,
introducing oxidant in the second exothermic oxidation or partial
oxidation reaction mode, and mixing same with other gases in the second
exothermic oxidation and partial oxidation mode, and directing resultant
oxidized gases to the first endothermic dehydrogenation reaction mode.