A high-temperature solution process for polymerizing ethylene is
disclosed. The polymerization is performed in the presence of a
preassembled bimetallic Ziegler-Natta catalyst and an aluminum compound.
Molecular modeling calculations predict that the bimetallic Ziegler-Natta
catalyst will have good activity and improved stability versus
traditional Ziegler-Natta catalysts. This makes the catalyst especially
suitable for solution polymerization processes, which require a thermally
robust catalyst.