In the production of an alkylbenzaldehyde by a method comprising a step of
preparing a solution of complex of a starting alkylbenzene and a hydrogen
fluoride-boron trifluoride catalyst and a step of formylation by bringing
the solution of complex into contact with carbon monoxide, an
alkylbenzene having at least one primary alkyl group having two or more
carbon atoms on its benzene ring is used as the starting alkylbenzene.
The preparation of the solution of complex is carried out in the presence
of an aliphatic or alicyclic saturated hydrocarbon having 6 to 10 carbon
atoms which contains at least one tertiary carbon atom but contains no
quaternary carbon atom. By the combined use of the specific alkylbenzene
and the aliphatic or alicyclic saturated hydrocarbon, the
disproportionation of the alkylbenzene is prevented and the
alkylbenzaldehyde is produced at high yields.