A process for preparing olefin homopolymers or copolymers by
polymerization of at least one olefin in a hydrocarbon (mixture) in the
presence of a molar mass regulator, a mixed catalyst and a substance
which increases the electrical conductivity of the hydrocarbon (mixture)
and is soluble in the hydrocarbon or the mixture of hydrocarbons or which
reacts with components of the mixed catalyst, wherein the mixed catalyst
is obtainable by reaction of a magnesium alkoxide with titanium(IV)
halide and comprises titanium in the oxidation states four and three and
also an organic aluminum compound, where the molar ratio of Ti(IV) to
Ti(III) is from 100:1 to 1:100.The process makes it possible to prepare,
in particular, polyethylenes having an ultrahigh molecular weight. The
formation of deposits on the walls during the polymerization is
significantly reduced.