This invention is based upon the discovered that crosslinked core-shell
particles can be used as a filler in low cost emulsion styrene-butadiene
rubber (ESBR) with excellent results being attained. In fact, such
core-shell particle filled ESBR exhibits performance similar to silica
filled solution styrene-butadiene rubber (SSBR) in terms of dynamic
response, Payne effect, rebound and tan .delta. at 0.degree. C. and
100.degree. C. The utilization of such crosslinked core-shell particles
in rubber compounds offers the additional advantage of weight reduction
since the core-shell particles are significantly less dense than carbon
black or silica fillers. The use of the crosslinked core-shell polymers
of this invention in rubber formulations in place of silica also offers
the advantage of not needing any expensive silane coupling agents to
attain required levels of polymer/filler interaction. Accordingly, no
silane coupling agent is used in the rubber compounds of this invention
which leads to reduced cost. Cost can be further reduced by virtue of the
fact that compound mixing conditions can be substantially relaxed as
compared to mixing silica containing rubber formulations. The present
invention more specifically discloses A rubbery composition which is
comprised of (1) an emulsion styrene-butadiene rubber, (2) carbon black,
and (3) core-shell particles, wherein the core-shell particles are
comprised of (a) a crosslinked elastomeric core comprised of repeat units
that are derived from at least one diolefin monomer, and (b) a polymeric
shell which is derived from at least one vinyl aromatic monomer.