According to the invention, there is provided a novel soybean variety designated XB32A06. This invention thus relates to the seeds of soybean variety XB32A06, to the plants of soybean XB32A06 to plant parts of soybean variety XB32A06 and to methods for producing a soybean plant produced by crossing plants of the soybean variety XB32A06 with another soybean plant, using XB32A06 as either the male or the female parent.