Fluorovinyl ethers having the formula CFX.dbd.CXOCF.sub.2OR, wherein R is a C.sub.2 C.sub.6 linear, branched or C.sub.5 C.sub.6 cyclic (per)fluoroalkyl group, or a C.sub.2 C.sub.6 linear, branched (per)fluoro oxyalkyl group containing from one to three oxygen atoms; when R is fluoroalkyl or fluorooxyalkyl group as above defined, it can contain from 1 to 2 atoms, equal or different, selected from the following: H, Cl, Br, I; X.dbd.F, H; and homopolymers or polymers obtainable polymerizing said Fluorovinyl ethers with at least another polymerizable monomer.