A method for calculating power flow solution of a power transmission network with unified power flow controllers is adapted to calculate the power flow on a large-scale power transmission network. The unified power flow controller has a series transformer, a series converter, a direct current coupling capacitor, a shunt converter, and a series transformer. The shunt transformer is connected electrically to a sending-end bus. The series transformer is connected electrically to the sending-end bus and a receiving-end bus. The unified power flow controller is represented by equivalent active and reactive loads on the sending-end and receiving-end buses of the power transmission network.