A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas, such as a syngas, contacts a water gas shift ("WGS") catalyst, in the presence of water, preferably at a temperature of less than about 450.degree. C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) at least one of Rh, Ni, Pt, their oxides and mixtures thereof, b) at least one of Cu, Ag, Au, their oxides and mixtures thereof; and c) at least one of K, Cs, Sc, Y, Ti, Zr, V, Mo, Re, Fe, Ru, Co, Ir, Pd, Cd, In, Ge, Sn, Pb, Sb, Te, La, Ce, Pr, Nd, Sm, Eu, their oxides and mixtures thereof. Another disclosed catalyst formulation comprises Rh, its oxides or mixtures thereof, Pt, its oxides or mixtures thereof and Ag, its oxides or mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, pervoskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.