The present invention relates to anti-wrinkle fabric treatment compositions comprising: a) from about 0.01% to about 20% by weight, of a cationic silicone polymer or copolymer having the formula: [CAP]-Z.sub.m-[CAP] wherein each Z unit comprises at least one secondary, tertiary, or quaternary amino moiety, or mixtures thereof; [CAP] is a backbone termination or truncation unit; m is from 1 to 50. b) from about 1% to about 30% by weight, of a scavenger effective in scavenging compounds comprising an anionic unit; and c) the balance a carrier system. In addition, the present invention relates to fabric rinse additive compositions comprising: a) from about 0.01% to about 20% by weight, of a cationic silicone polymer or copolymer having the formula: [CAP]-Z.sub.m-[CAP] wherein each Z unit comprises at least one secondary, tertiary, or quaternary amino moiety, or mixtures thereof; [CAP] is a backbone termination or truncation unit; m is from 1 to 50. b) from about 1% to about 30% by weight, a minor component selected from the group consisting of emulsifiers, perfumes, dyes, preservatives or mixtures thereof; and c) the balance a carrier system.