Disclosed herein is an appliance for use in an oral cavity, wherein the appliance comprises a polymeric shell that comprises a polymeric mixture, and further wherein the polymeric shell has cavities designed to receive teeth. Disclosed herein too is a method for maintaining or repositioning teeth in the oral cavity comprising placing an appliance in a patient's mouth, wherein the appliance comprises a polymeric shell that comprises a polymeric mixture, and further wherein the polymeric shell has cavities designed to receive teeth.