In order to maximize the production of propylene when the external supply
of ethylene is limited, the C.sub.4 cut from a hydrocarbon cracking
process is first subjected to autometathesis prior to any isobutylene
removal and without any ethylene addition. This favors the reactions
which produce propylene and pentenes. The ethylene and propylene produced
are then removed leaving a stream of the C.sub.4's and heavier
components. The C.sub.5 and heavier components are then removed leaving a
mixture of 1-butene, 2-butene, isobutylene, and iso- and normal butanes.
The isobutylene is next removed preferably by a catalytic distillation
hydroisomerization de-isobutyleneizer. The isobutylene-free C.sub.4
stream is then mixed with the product ethylene removed from the
autometathesis product together with any fresh external ethylene needed
and subjected to conventional metathesis producing additional propylene.