The present invention relates to a non-aqueous electrolyte additive for
improving safety and a lithium secondary battery comprising the same, and
more particularly to a non-aqueous electrolyte additive that can improve
cycle life and safety properties of a lithium ion secondary
battery.According to the present invention, an organometallic compound
represented by the Chemical Formula 1 is added to a non-aqueous
electrolyte of a battery as an additive, and thus if a battery voltage is
out of normal operation voltage range due to a short circuit and
overcharge of a battery, etc., the non-aqueous electrolyte additive
decomposes and a part of the decomposed additive polymerizes to form an
insulating film on a cathode surface, and a part of the metal reacts with
an insulating film formed on a cathode surface to improve thermal
stability of the battery, thereby improving safety of the battery.
Furthermore, in case of a short circuit a part of the metal oxide of the
additive is removed an activity of lithium or is reduced movement speed
of lithium by reacting with lithium rushed from an anode to a cathode,
and thus safety of the battery can be obtained on a short circuit by
delaying a flow of current.