The present invention comprises a polymer composition which is comprised of subcompositions which are separately stable within the polymer composition and methods of making the polymer compositions. These polymer compositions may be useful as coatings for paper, food packaging, vinyl, plastics, man-made substrates, wood and metal. An advantage of these polymer composition is that they are aqueous non-fluorocarbon polymers, which are less pollutive than state of the art polymer coatings.