An object of the invention is to provide an electrode system for optical modulation of an optical modulator to reduce a thickness "E" of an electrode required for velocity matching and for reducing a propagation loss in the electrode. A substrate 2 is made of an electrooptic material and has one and the other main faces 2a, 2b opposing each other. An electrode system 20A is provided on the substrate 2 for applying a voltage for modulating light propagating in optical waveguides 6A and 6B. The electrode system 20A includes ground electrodes 3A, 3B and a signal electrode 4. A ratio "W/G" of a width "W" of the signal electrode 4 to a gap "G" between the ground and signal electrodes is 0.8 or higher. Preferably, the substrate 2 has a thickness "T" of 20 .mu.m or larger, in a region where the optical waveguides 6A and 6B are provided.