An acrylic composition includes the reaction product of an acrylic polymer
and carbon dioxide. The acrylic polymer includes the reaction product of
a functionalized monomer, a first compound reactive with the
functionalized monomer to form a functionalized intermediate, and a
highly branched, polyfunctional core molecule reactive with the
functionalized intermediate. The first compound includes vinyl
functionality reactive with the functionalized monomer. The first
compound also includes epoxy functionality. The carbon dioxide is
reactive with the acrylic polymer to form a carbonate-functional acrylic
polymer. The acrylic composition is highly-branched and, when used in
coating compositions in combination with a suitable cross-linking agent,
enhances recoat adhesion and produces cured films that have optimum
scratch, mar, and chip performance, and acid etch resistance.