Polyester compositions that provide a higher throughput in calendering
processes may be prepared from a polyester having crystallization half
time of at least 5 minutes, an inherent viscosity of about 0.55 to about
0.75 dL/g, a branching monomer, and a release additive. The polyester
compositions show a combination of excellent melt strength with good
shear response that permits higher calendering line speeds before melt
fracture occurs. Also disclosed are processes for film or sheet by
calendering the above compositions and the film or sheet produced
therefrom. The polyester compositions, film, or sheet also may include
plasticizers and/or flame retardants to increase their flexibility and
enable their use in commercial applications requiring flame resistance.
The film and sheet have excellent appearance and can be used in a wide
range of decorative and packaging applications.