The present invention is a novel method whereby voids or solid opens at the bottom of via can be avoided without drastically altering the resistivity or parasitic capacitances of the whole metal interconnect system. The invention includes in one embodiment a process of forming interconnects and vias in a microelectronic circuit structure. This process includes implanting and/or alloying an impurity element in the local area of the top surface of a metal interconnect at the bottom of a via. Doping may be done before or after formation of the via. After the via is formed, it is filled with a metal such as copper. Another embodiment of the invention is a microelectronic circuit structure manufactured by the aforementioned method.