Surface-modified nanoparticles of boehmite, and methods for preparing the
same. Aluminum oxyhydroxide nanoparticles are surface modified by
reaction with selected amounts of organic acids. In particular, the
nanoparticle surface is modified by reactions with two or more different
carboxylic acids, at least one of which is an organic carboxylic acid.
The product is a surface modified boehmite nanoparticle that has an
inorganic aluminum oxyhydroxide core, or part aluminum oxyhydroxide core
and a surface-bonded organic shell. Organic carboxylic acids of this
invention contain at least one carboxylic acid group and one
carbon-hydrogen bond. One embodiment of this invention provides boehmite
nanoparticles that have been surface modified with two or more acids one
of which additional carries at least one reactive functional group.
Another embodiment of this invention provides boehmite nanoparticles that
have been surface modified with multiple acids one of which has molecular
weight or average molecular weight greater than or equal to 500 Daltons.
Yet, another embodiment of this invention provides boehmite nanoparticles
that are surface modified with two or more acids one of which is
hydrophobic in nature and has solubility in water of less than 15 by
weight. The products of the methods of this invention have specific
useful properties when used in mixture with liquids, as filler in solids,
or as stand-alone entities.