Combinations of essentially nonvolatile, unsaturated ethers and/or esters, and small proportions of low glass transition temperature (Tg) latex reins, as replacements for volatile organic compounds (VOCs) as coalescents and optionally reactive amines (as replacements for conventionally employed volatile amines/ammonia neutralizers, respectively), provides economical, low/no VOC-containing acrylic, styrenic copolymer, polyester, polyurethane and vinyl copolymer latex based coatings, paints, and inks; which out/perform their conventional counterparts.