The present invention provides polyurethanes including a reaction product
of components including: (a) an isocyanate functional urethane prepolymer
comprising a reaction product of components including: (i) about 1
equivalent of at least one polyisocyanate; and (ii) about 0.1 to about
0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b)
about 0.05 to about 0.9 equivalents of at least one branched polyol
having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to
about 0.45 equivalents of at least one diol having 2 to 18 carbon atoms,
wherein the reaction product components are essentially free of polyester
polyol and polyether polyol; compositions, coatings and articles made
therefrom and methods of making the same.