The present invention comprises a method of treating an off-gas stream
from a refining process to remove sulfur compounds. A portion of the
off-gas stream containing hydrogen sulfide is injected at the front end
of the thermal reactor and in at least one other location downstream of
the thermal reactor. A ratio of hydrogen sulfide to sulfur dioxide at the
outlet of the thermal reactor is less than the stoichiometric
requirement. The ratio is adjusted downstream of the thermal reactor so
that a ratio of hydrogen sulfide to sulfur dioxide is maintained
substantially in excess of the stoichiometric requirement for a Claus
reaction. The tail gas, containing hydrogen sulfide but virtually no
sulfur dioxide, is treated by a process including removal of water and
introducing sulfur dioxide into the tail gas in a stoichiometricly
balanced quantity and processing the tail gas in a Claus reactor.