A process of producing aldehydes in a continuous hydroformylation process
of continuously reacting an olefinic unsaturated compound with carbon
monoxide and hydrogen in the presence of a rhodium-phosphite based
complex catalyst and continuously separating at least one component from
a reaction product, the process being characterized in that at least a
part of an aldehyde product and water are taken out as a mixed vapor flow
from a catalyst-existent region in the process, and at least a part
thereof is fed outside the catalyst-existent region as it stands as the
vapor or as a condensate after cooling, to reduce the water concentration
within the catalyst-existent region, whereby decomposition of phosphite
ligands in the hydroformylation process of olefins is suppressed.