The present invention includes ultraviolet curable compositions preferably
containing discrete, crystalline zirconia nanoparticles with reactive, or
copolymerizable, surface modification, in a polymerizable
monomer/oligomer resin mixture. It is believed that copolymerizable
surface modification provides a functional group that enables the
functionalized particle to co-polmerize with the reactive monomers,
oligomers, and crosslinkers in the formulation. Relative to surface
modification of the nanoparticles, acrylate functionality is preferred
over methacrylate functionality. On the other hand, methacrylate
functionality is preferred over non-reactive, or nonpolymerizable,
functionality. As the nanocomposite cures, the resultant network is
heavily crosslinked by selection of raw materials with substantial
acrylate functionality.