A process for the production of ethylbenzene by the ethylation of benzene
in the critical phase over a molecular sieve aromatic alkylation
catalyst. An aromatic feedstock having a benzene content of at least 90
wt. % is supplied into a reaction zone into contact with a zeolite beta
alkylation catalyst having a silica/alumina ratio within the range of
20-500, specifically 50-150. The alkylation catalyst is a zeolite beta
specifically a lanthanum-modified zeolite beta. Ethylene is supplied to
the reaction zone to provide a benzene/ethylene mole ratio of 1-15. The
reaction zone is operated under conditions in which benzene is in the
supercritical phase to produce an alkylation product containing
ethylbenzene as a primary product with heavier alkylated by-products of
no more than 60 wt. % of the ethylbenzene. The alkylation product is
recovered from the reaction zone and supplied to a separation and
recovery zone to separate ethylbenzene from a polyalkylated component
including diethylbenzene. At least a portion of the polyalkylated
component is supplied to a transalkylation reaction zone containing a
molecular sieve transalkylation catalyst. The transalkylation reaction
zone contains a zeolite Y catalyst and is operated under liquid phase
conditions.