This invention relates to the use of a supplemental promoter in
conjunction with a noble-metal-containing catalyst comprising a carbon
support in catalyzing liquid phase oxidation reactions, a process for
making of an improved catalyst comprising such a supplemental promoter,
and an improved catalyst comprising such a supplemental promoter. In a
particularly preferred embodiment, a supplemental promoter (most
preferably bismuth or tellurium) is used in conjunction with a
noble-metal-containing catalyst comprising a carbon support in a liquid
phase oxidation process wherein N-(phosphonomethyl)iminodiacetic acid
(i.e., "PMIDA") or a salt thereof is oxidized to form
N-(phosphonomethyl)glycine (i.e., "glyphosate") or a salt thereof. The
benefits of such a process include increased oxidation of the
formaldehyde and formic acid by-products, and, consequently, decreased
final concentrations of those by-products as well as other undesirable
by-products, most notably N-methyl-N-(phosphonomethyl)glycine (i.e.,
"NMG").