There is here disclosed a wastewater treating technique for treating nitrogen compounds in a for-treatment wastewater by an electrochemical technique, wherein at least portions of a pair of electrodes is immersed in the for-treatment wastewater; a material of one electrode constituting an anode is an insoluble conductor; and a material of the other electrode constituting a cathode is an element in the group VIII of the periodic table, a conductor containing the element in the group VIII, or a conductor covered with the element in the same group or the conductor containing the element in the same group.