A process for manufacturing a polymer having a molecular weight in excess
of 5,000, and preferably in excess of 40,000, comprises, producing a
polymerized reaction mass in which the polymer is dispersed, the reaction
mass including solvent(s), unreacted monomer and other unwanted
contaminants; feeding the reaction mass to a means for disentangling the
polymer's molecules to produce a modified polymer in the reaction mass;
feeding the modified polymer in the reaction mass to a polymer-recovering
means; removing the unwanted volatiles and other byproducts; and,
recovering a high molecular weight substantially pure modified polymer
having substantially the same molecular weight as the polymer fed to the
disentangling means and a viscosity at least 10% lower than that of the
polymer fed to the disentangling means.