A method for dimerizing isobutene, wherein, in dimerizing conditions, the
isobutene is brought into contact with a porous cation exchange resin
comprising a styrene polymer, which is cross-linked with divinyl benzene,
and any sulphonic acid groups adhering to the polymer. The harmful
deactivation of this catalyst, which is caused by the accumulation of the
oligomers and polymers of isobutene and other C.sub.4-olefins in the
cation exchange resin catalyst, is essentially decreased by selecting the
cation exchange resin from a group including cation exchange resins, the
acid,capacity of which is 4.7 equivalents/kg at a minimum, and the
portion of divinyl benzene units of which is 5% by weight at a minimum
and smaller than 20% by weight.