An electrolytic plating method and composition for electrolytically
plating Cu onto a semiconductor integrated circuit substrate having
submicron-sized interconnect features. The composition comprises a source
of Cu ions and a suppressor compound comprising polyether groups. The
method involves superfilling by rapid bottom-up deposition at a superfill
speed by which Cu deposition in a vertical direction from the bottoms of
the features to the top openings of the features is substantially greater
than Cu deposition on the side walls.