A method and apparatus for purifying carboxylic acids is disclosed. A
mixture containing crude carboxylic acid is contacted with a selective
crystallization solvent to form a slurry of a salt complex of the
carboxylic acid and the selective crystallization solvent. The salt
complex is recovered and optionally processed to recover the free
carboxylic acid. The method and apparatus of the invention is
particularly suitable for purifying aromatic dicarboxylic acids such as
terephthalic acid. The present invention also reduces contamination by
carboxybenaldehyde isomers in crude phthalic acids by oxidizing the
carboxybenzaldehyde to the corresponding phthalic acid.