The present invention includes compositions suitable for tire treads or
sidewalls and other articles where abrasion resistance and flexibility
are desirable. The invention includes a tire tread or sidewall made by
combining a filler; a sulfur cure system; optionally at least one
secondary rubber; and at least one halogenated terpolymer of C.sub.4 to
C.sub.8 isoolefin derived units, C.sub.4 to C.sub.14 multiolefin derived
units, and p-alkylstyrene derived units. Examples of suitable fillers
include carbon black, silica, and combinations thereof. The present
invention also includes a method of producing an elastomeric terpolymer
composition comprising combining in a diluent C.sub.4 to C.sub.8
isoolefin monomers, C.sub.4 to C.sub.14 multiolefin monomers, and
p-alkylstyrene monomers in the presence of a Lewis acid and at least one
initiator to produce the terpolymer. Examples of suitable initiators
include cumyl compounds and or halogenated organic compounds, especially
secondary or tertiary halogenated compounds such as, for example,
t-butylchloride, 2-acetyl-2-phenylpropane (cumyl acetate), 2-methoxy
2-phenyl propane (cumylmethyl-ether), 1,4-di(2-methoxy-2-propyl)benzene
(di(cumylmethyl ether)); the cumyl halides, particularly the chlorides,
such as, for example 2-chloro-2-phenylpropane, cumyl chloride
(1-chloro-1-methylethyl)benzene), 1,4-di(2-chloro-2-propyl)benzene
(di(cumylchloride)), and 1,3,5-tri(2-chloro-2-propyl)benzene
(tri(cumylchloride)); the aliphatic halides, particularly the chlorides,
such as, for example, 2-chloro-2,4,4-trimethylpentane (TMPCl), and
2-bromo-2,4,4-trimethylpentane (TMPBr).