This invention relates to preparation of nanocomposites comprised of
elastomer and a dispersion of an at least partially exfoliated water
swellable clay and to rubber compositions containing such nanocomposite
and articles of manufacture which contain at least one component thereof.
The nanocomposite is prepared by addition of a water suspension of water
swellable clay particles to an anionic aqueous emulsion of elastomer
particles to form a mixture to which an amine having at least two amine
centers is added to intercalate and at least partially exfoliate the
water swelled clay particles by an ion exchange within the galleries of
the multilayered clay with cation exchangeable ion(s) and to aid in
coagulating the elastomer and resultant clay particles to form said
nanocomposite.