The invention is directed to processes and apparatuses for the production of chemical compounds, in particular fermentation products. According to the invention there is provided a process for the production of one or more chemical substances, which process comprises a fermentation step, wherein said substances are formed; and a separation step, wherein at least one pair of electrodes is used to induce a precipitation of said substances, which pair comprises at least one precipitation electrode and at least one counter electrode, through which an electric current is directed is used to precipitate said one or more substances.