Disclosed is a process for the preparation of a high stereospecific
(isotactic) polybutylene polymer comprising the step of polymerizing a
reactive monomer, 1-butene, which is used or is not used as a solvent, in
the presence of catalyst and inert gas. According to the present
invention, it is possible to prepare a high stereospecific polybutylene
polymer in much higher activity than that of any other known processes
for the preparation of a high stereospecific polybutylene polymer. The
high stereospecific polybutylene polymer according to the present
invention is a homopolymer of 1-butene, or a copolymer containing
a-olefin and up to 40% by weight of a comonomer, wherein titanium in the
catalyst residues is not detected in the ppm level, stereospecificity
(Isotactic Index, mmmm %) determined by .sup.13C-NMR is 96 or more,
molecular weight distribution (Mw/Mn) is 3-6, and molecular weight
distribution (Mw/Mn) can be controlled to 8 or more.