There is provided a porous membrane of vinylidene fluoride resin which has
pores of appropriate size and distribution and also excellent mechanical
strength represented by tensile strength and elongation at break and is
useful as a microfiltration membrane or a separator for batteries. The
porous membrane of vinylidene fluoride resin is characterized by the
presence in mixture of a crystalline oriented portion and a crystalline
non-oriented portion as confirmed by X-ray diffraction, and is produced
by subjecting a melt-extruded composition obtained by mixing a vinylidene
fluoride resin having a molecular weight distribution which is
appropriately broad and high as a whole with a plasticizer and a good
solvent for vinylidene fluoride resin, to cooling for solidification from
one surface, extraction of the plasticizer and stretching.