A method of making particles suitable for use as toners includes forming a
mixture of sulfonated polyester resin, a colorant dispersion and
optionally a wax dispersion, homogenizing the mixture, adding a coagulant
to the mixture to aggregate the mixture to form aggregated particles, and
coalescing the aggregated particles to form coalesced particles. In the
method, when a predetermined average particle size is achieved during the
aggregation and/or coalescing step, a complexing agent that complexes
with ions of the coagulant is added in an amount effective to
substantially halt any further particle growth. The complexing agent is
believed to halt further growth by complexing with free coagulant ions
still in the solution.