Provided are an exhaust treatment catalyst and an exhaust article
containing the catalyst. The catalyst comprises: (a) a carrier; (b) a
first layer deposited on the carrier, said first layer comprising
substantially only at least one refractive metal oxide; (c) a second
layer deposited on the first layer, said second layer comprising
substantially only at least one oxygen storage component and at least one
binder therefor; and (d) a third layer deposited on the second layer,
said third layer comprising at least one layer of one or more platinum
group metal components supported on a refractory metal oxide support.
Optionally, a fourth layer is deposited on the third layer wherein the
fourth layer comprises one or more platinum group metal components
supported on a refractory metal oxide support. As a further option, an
overcoat layer may be deposited on the third or fourth layer wherein the
overcoat layer comprises a catalyst poison sorbent. Also provided are
methods for preparing the catalyst and methods for monitoring the exhaust
storage capacity of an exhaust article containing the catalyst.