A process for preparing an aqueous styrene-butadiene polymer dispersion by
free-radical aqueous emulsion polymerization of a monomer mixture M
comprising styrene, butadiene, and if desired up to 30% by weight, based
on 100% by weight of monomers, of ethylenically unsaturated comonomers
other than styrene and butadiene; in a polymerization vessel by a monomer
feed technique in the presence of a regulator system containing, based on
100% by weight of monomers, from 0.02 to 0.5% by weight of at least one
hydrocarbon HC having from 6 to 20 carbon atoms, selected from compounds
which on abstraction of a hydrogen atom form a pentadienyl radical or
1-phenylallyl radical, and .alpha.-methylstyrene dimer, and from 0.3 to
2% by weight of an organic compound S containing at least one SH group
wherein at least 30%, preferably at least 50%, in particular at least
80%, and with particular preference the entirety (or >95%) of
hydrocarbon HC is included in the initial charge to the polymerization
vessel.