Electrophotographic charging devices and methods for charging a receptor with a solid state charging device are disclosed. In an exemplary embodiment, the solid state charging device can include a dielectric layer, a first electrode disposed adjacent to a first surface of the dielectric layer, and a second electrode having a first surface disposed adjacent to a second surface of the dielectric layer. The solid state charging device can further include a plurality of nanostructures each having an end in electrical contact with a second surface of the second electrode. The exemplary solid state charging devices including the nanostructures can use less voltage than conventional charging devices, produce a reduced amount of oxidizing agents, such as, ozone and NO.sub.x, and/or operate at a lower temperature.