The average propylene cycle selectivity of an oxygenate to propylene (OTP)
process using a dual-function oxygenate conversion catalyst is
substantially enhanced by the use of a combination of: 1) moving bed
reactor technology in the hydrocarbon synthesis portion of the OTP flow
scheme in lieu of the fixed bed technology of the prior art; 2) a
hydrothermally stabilized and dual-functional catalyst system comprising
a molecular sieve having dual-function capability dispersed in a
phosphorus-modified alumina matrix containing labile phosphorus and/or
aluminum anions; and 3) a catalyst on-stream cycle time of 400 hours or
less. These provisions stabilize the catalyst against hydrothermal
deactivation and hold the build-up of coke deposits on the catalyst to a
level which does not substantially degrade dual-function catalyst
activity, oxygenate conversion and propylene selectivity, thereby
enabling maintenance of average propylene cycle yield near or at
essentially start-of-cycle levels.