A method for carrying out the continuous polymerization of a monomer in a
carbon dioxide reaction medium comprises the steps of: (a) providing an
apparatus including a continuous reaction vessel and a separator; (b)
carrying out a polymerization reaction in the reaction vessel by
combining a monomer and a carbon dioxide reaction medium therein (and
preferably by also combining an initiator therein), wherein the reaction
medium is a liquid or supercritical fluid, and wherein the reaction
produces a solid polymer product in the reaction vessel; then (c)
withdrawing a continuous effluent stream from the reaction vessel during
the polymerization reaction, wherein the effluent stream is maintained as
a liquid or supercritical fluid; then (d) passing the continuous effluent
stream through the separator and separating the solid polymer therefrom
while maintaining at least a portion of the effluent stream as a liquid
or supercritical fluid; and then (e) returning at least a portion of the
continuous effluent stream to the reaction vessel while maintaining the
effluent stream as a liquid or supercritical fluid. The need for
significant recompression of the continuous effluent stream prior to
return to the reaction vessel is thereby minimized. Apparatus for
carrying out such methods is also disclosed.