A liquid crystal display panel includes a first substrate, a second substrate opposite the first substrate and a liquid crystal layer. The first substrate includes a lower substrate, a first buffer layer formed on the lower substrate and a first alignment layer formed on the first buffer layer. The first buffer layer includes a polymer-like carbon and the first alignment layer includes a diamond-like carbon thin film containing fluorine. The second substrate includes an upper substrate, a second buffer layer formed on the upper substrate and a second alignment layer formed on the second buffer layer. The second buffer layer includes the polymer-like carbon thin film and the second alignment layer includes the diamond-like carbon thin film containing fluorine. The liquid crystal display panel has improved light transmittance and a low probability of separation between the alignment layer and the substrate.