The present invention relates to use of selective oxidation to oxidize
silicon in the presence of tungsten and/or tungsten nitride in memory
cells and memory arrays. This technique is especially useful in
monolithic three dimensional memory arrays. In one aspect of the
invention, the silicon of a diode-antifuse memory cell is selectively
oxidized to repair etch damage and reduce leakage, while exposed tungsten
of adjacent conductors and tungsten nitride of a barrier layer are not
oxidized. In some embodiments, selective oxidation may be useful for gap
fill. In another aspect of the invention, TFT arrays made up of charge
storage memory cells comprising a polysilicon/tungsten nitride/tungsten
gate can be subjected to selective oxidation to passivate the gate
polysilicon and reduce leakage.