A method of reducing sulfur dioxide emissions of a circulating fluidized
bed boiler. Sulfur-containing carbonaceous fuel is fed to a furnace of
the boiler, and calcium carbonate is fed to the furnace at a rate
relative to the first stream such that the molar ratio of calcium in the
second stream to sulfur in the first stream is at most about 1.0. The
fuel is combined so that the sulfur is oxidized to form sulfur dioxide.
The calcium carbonate is calcined to form calcium oxide and the calcium
oxide is used to sulfate the sulfur dioxide to form calcium sulfate. Flue
gas particles are separated using a hot loop separator, and the separated
particles are returned to the furnace. A sulfur-reduction stage
downstream of the furnace further reduces the sulfur content of the flue
gases.