A process for preparing butadiene, comprising nonoxidatively
dehydrogenating n-butane from a stream (a) in a first dehydrogenation
zone to obtain stream (b) comprising 1-butene and 2-butene; oxidatively
dehydrogenating the 1-butene and 2-butene of (b) in the presence of an
oxygenous gas in a second dehydrogenation zone to obtain stream (c)
comprising n-butane, butadiene, hydrogen, carbon dioxide, and steam;
compressing and cooling (c) to obtain stream (d2) comprising n-butane,
butadiene, hydrogen, carbon dioxide, and steam; extractively distilling
(d2) into stream (e1) comprising butadiene and stream (e2) comprising
n-butane, hydrogen, carbon dioxide, and steam; compressing and cooling
(e2) to obtain stream (f1) comprising n-butane and water and stream (f2)
comprising n-butane, hydrogen, and carbon dioxide; cooling (f2) to obtain
stream (g1) comprising n-butane and stream (g2) comprising carbon dioxide
and hydrogen; phase separating water from (f1) to obtain stream (h1)
comprising n-butane; and recycling (h1) into the first dehydrogenation
zone.